| First Round |
| 1 Daniil Medvedev |
| Bye |
| First Round |
| 3 Matteo Berrettini |
| Bye |
| First Round |
| 2 Karen Khachanov |
| Bye |
| First Round |
| 4 Borna Coric |
| Bye |
| First Round | |||||
| 7 Adrian Mannarino | |||||
| Stefano Travaglia | |||||
| Pre-Match | |||||
| First Round | |||||
| 6 Mikhail Kukushkin | |||||
| Jannik Sinner | |||||
| Pre-Match | |||||
| First Round |
| 1 David Goffin |
| Bye |
| First Round |
| 3 Benoit Paire |
| Bye |
| First Round |
| 2 Nikoloz Basilashvili |
| Bye |
| First Round |
| 4 Lucas Pouille |
| Bye |
| First Round | |||||
| Antoine Hoang | |||||
| Cedrik-Marcel Stebe | |||||
| Pre-Match | |||||
| First Round | |||||
| 5 Fernando Verdasco | |||||
| Steve Darcis | |||||
| Pre-Match | |||||
| First Round | |||||
| Peter Gojowczyk | |||||
| Filip Krajinovic | |||||
| Pre-Match | |||||
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