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| WTA Finals Guadalajara | ||
| Surface: Hard | Date: Nov. 10 - Nov. 17 | Seed: 8 |
| Round | Opponent | W / L | Result |
| Round Robin | Barbora Krejcikova | Win | 6-3, 6-4 6-4, 6-0 4-6, 4-6 |
| Round Robin | Karolina Pliskova | Win | 6-3, 6-4 6-4, 6-0 4-6, 4-6 |
| Round Robin | Garbine Muguruza | Loss | 6-3, 6-4 6-4, 6-0 4-6, 4-6 |
| Semifinals | Maria Sakkari | Win | 6-1, 3-6, 6-3 |
| Final | Garbine Muguruza | Loss | 3-6, 5-7 |
| Transylvania Open | ||
| Surface: Clay | Date: Oct. 25 - Oct. 31 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Aleksandra Krunic | Win | 6-3, 7-5 |
| Second Round | Alison Van Uytvanck | Win | 6-3, 6-4 |
| Quarterfinals | Anhelina Kalinina | Win | 6-3, 6-1 |
| Semifinals | Rebecca Peterson | Win | 6-3, 6-2 |
| Final | Simona Halep | Win | 6-2, 6-3 |
| VTB Kremlin Cup | ||
| Surface: Hard | Date: Oct. 18 - Oct. 24 | Seed: 9 |
| Round | Opponent | W / L | Result |
| First Round | Katerina Siniakova | Win | 6-3, 6-3 |
| Second Round | Andrea Petkovic | Win | 6-1, 6-4 |
| Quarterfinals | Garbine Muguruza | Win | 6-1, 6-1 |
| Semifinals | Marketa Vondrousova | Win | 6-3, 6-4 |
| Final | Ekaterina Alexandrova | Win | 4-6, 6-4, 7-5 |
| BNP Paribas Open | ||
| Surface: Hard | Date: Oct. 6 - Oct. 17 | Seed: 18 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Martina Trevisan | Win | 6-3, 5-2 Retired |
| Third Round | Bianca Andreescu | Win | 7-6 (7-5), 6-3 |
| Fourth Round | Beatriz Haddad Maia | Win | 6-0, 6-2 |
| Quarterfinals | Ons Jabeur | Loss | 5-7, 3-6 |
| Chicago Fall Tennis Classic | ||
| Surface: Hard | Date: Sep. 27 - Oct. 3 | Seed: 11 |
| Round | Opponent | W / L | Result |
| First Round | Madison Brengle | Win | 6-4, 6-3 |
| Second Round | Mai Hontama | Loss | Retired |
| J&T Banka Ostrava Open 2021 | ||
| Surface: Hard | Date: Sep. 20 - Sep. 26 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Sorana Cirstea | Win | 6-4, 6-4 |
| Second Round | Paula Badosa | Win | 6-3, 6-4 |
| Quarterfinals | Belinda Bencic | Win | 6-4, 6-3 |
| Semifinals | Petra Kvitova | Win | 6-0, 6-4 |
| Final | Maria Sakkari | Win | 6-2, 7-5 |
| US Open | ||
| Surface: Hard | Date: Aug. 30 - Sep. 12 | Seed: 28 |
| Round | Opponent | W / L | Result |
| First Round | Samantha Stosur | Win | 6-3, 6-0 |
| Second Round | Jil Teichmann | Win | 6-4, 6-1 |
| Third Round | Iga Swiatek | Loss | 3-6, 6-4, 3-6 |
| Cleveland Championships | ||
| Surface: Hard | Date: Aug. 22 - Aug. 28 | Seed: 2 |
| Round | Opponent | W / L | Result |
| First Round | Lauren Davis | Win | 1-6, 6-0, 6-0 |
| Second Round | Caroline Garcia | Win | 6-3, 6-3 |
| Quarterfinals | Katerina Siniakova | Win | 6-3, 5-7, 6-2 |
| Semifinals | Sara Sorribes Tormo | Win | 6-4, 6-4 |
| Final | Irina-Camelia Begu | Win | 7-6 (7-5), 6-4 |
| Western & Southern Open | ||
| Surface: Hard | Date: Aug. 15 - Aug. 22 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Ons Jabeur | Loss | 2-6, 6-4, 5-7 |
| National Bank Open presented by Rogers | ||
| Surface: Hard | Date: Aug. 9 - Aug. 15 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Jessica Pegula | Loss | 7-5, 3-6, 3-6 |
| Wimbledon | ||
| Surface: Grass | Date: Jun. 28 - Jul. 11 | Seed: 24 |
| Round | Opponent | W / L | Result |
| First Round | Marketa Vondrousova | Loss | 6-2, 4-6, 2-6 |
| Nature Valley International | ||
| Surface: Grass | Date: Jun. 21 - Jun. 26 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Svetlana Kuznetsova | Win | 6-4, 3-6, 6-3 |
| Second Round | Bianca Andreescu | Win | 6-3, 6-3 |
| Quarterfinals | Viktorija Golubic | Win | 2-6, 7-6 (7-2), 7-5 |
| Semifinals | Camila Giorgi | Win | 5-4 Retired |
| Final | Jelena Ostapenko | Loss | 3-6, 3-6 |
| Roland Garros | ||
| Surface: Red Clay | Date: May 30 - Jun. 13 | Seed: 30 |
| Round | Opponent | W / L | Result |
| First Round | Viktorija Golubic | Win | 6-7 (4-7), 7-6 (7-5), 6-0 |
| Second Round | Kristina Mladenovic | Win | 6-2, 6-0 |
| Third Round | Iga Swiatek | Loss | 6-7 (4-7), 0-6 |
| Mutua Madrid Open | ||
| Surface: Hard | Date: Apr. 29 - May 9 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Nina Stojanovic | Win | 7-6 (7-4), 7-5 |
| Second Round | Maria Sakkari | Loss | 3-6, 1-6 |
| Porsche Tennis Grand Prix | ||
| Surface: Clay | Date: Apr. 19 - Apr. 25 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Julia Middendorf | Win | 6-2, 6-3 |
| Second Round | Sofia Kenin | Win | 7-5, 6-4 |
| Quarterfinals | Aryna Sabalenka | Loss | 5-7, 6-4, 1-6 |
| Miami Open presented by Itau | ||
| Surface: Hard | Date: Mar. 23 - Apr. 4 | Seed: 22 |
| Round | Opponent | W / L | Result |
| First Round | Bye | ||
| Second Round | Sorana Cirstea | Win | 6-3, 4-6, 6-3 |
| Third Round | Elise Mertens | Loss | 2-6, 6-0, 2-6 |
| Dubai Duty Free Tennis Championships | ||
| Surface: Hard | Date: Mar. 7 - Mar. 13 | Seed: 15 |
| Round | Opponent | W / L | Result |
| First Round | Timea Babos | Win | 6-2, 6-1 |
| Second Round | Sorana Cirstea | Win | 6-4, 7-5 |
| Third Round | Aryna Sabalenka | Loss | 3-6, 2-6 |
| Qatar Total Open 2021 | ||
| Surface: Hard | Date: Mar. 1 - Mar. 6 | Seed: None |
| Round | Opponent | W / L | Result |
| First Round | Jennifer Brady | Win | 6-1, 6-2 |
| Second Round | Angelique Kerber | Win | 6-1, 6-4 |
| Quarterfinals | Petra Kvitova | Loss | 3-6, 6-3, 2-6 |
| Australian Open | ||
| Surface: Hard | Date: Feb. 8 - Feb. 21 | Seed: 21 |
| Round | Opponent | W / L | Result |
| First Round | Aliaksandra Sasnovich | Win | 7-5, 6-2 |
| Second Round | Heather Watson | Win | 6-7 (5-7), 6-4, 6-2 |
| Third Round | Shelby Rogers | Loss | 4-6, 3-6 |
| Grampians Trophy | ||
| Surface: Hard | Date: Feb. 3 - Feb. 7 | Seed: 6 |
| Round | Opponent | W / L | Result |
| First Round | Christina McHale | Win | 6-1, 6-3 |
| Second Round | Bethanie Mattek-Sands | Win | 7-5, 7-5 |
| Quarterfinals | Victoria Azarenka | Win | Retired |
| Semifinals | Maria Sakkari | Win | 2-6, 6-3, 11-9 |
| Abu Dhabi WTA Women's Tennis Open | ||
| Surface: Hard | Date: Jan. 6 - Jan. 13 | Seed: 10 |
| Round | Opponent | W / L | Result |
| First Round | Veronika Kudermetova | Loss | 5-7, 1-6 |
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